Temperature and volume dependence of the viscosity of water and heavy water at low temperatures

被引:146
作者
Harris, KR [1 ]
Woolf, LA [1 ]
机构
[1] Univ New S Wales, Australian Def Force Acad, Sch Phys Environm & Math Sci, Univ Coll, Canberra, ACT 2600, Australia
关键词
D O I
10.1021/je049918m
中图分类号
O414.1 [热力学];
学科分类号
摘要
New measurements have been made for the viscosity (77) of light and heavy water between the temperatures of 255.65 K and 298.15 K at pressures up to approximately 375 MPa with a falling-body viscometer. A revised correlation function is used to represent the results as a function of temperature and molar volume (V) with a standard deviation of +/-0.2% for both H2O and D2O. The overall uncertainty is estimated at +/-1%. Comparison of the two sets of data shows that they are consistent with the correlation eta(D2O,T,V) = 1.0544eta(H2O,T - 6.498 K,V) where 1.0544 is the square root of ratio the molar masses and 6.498 K is the thermal offset proposed by Robinson and co-workers.
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页码:1064 / 1069
页数:6
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