Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); Crystal structure of [Re(MeP=CHBu(t))Cl(I)(CO)(PPh(3))(2)]

被引：32

作者：

Bedford, RB

Hill, AF

Jones, C

White, AJP

WiltonEly, JDET

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

[2] UNIV COLL SWANSEA,DEPT CHEM,SWANSEA SA2 8PP,W GLAM,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607016g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [Ru(P=CHBu(t))Cl(CA)(PPh(3))(2)] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe-CHBu(t))Cl(I)(CA)(PPh(3))(2)] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.

引用

页码：139 / 140

页数：2

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