Mechanistic investigation on the hydrogenation of imines by [p-(Me2CH)C6H4Me]RuH(NH2CHPhCHPhNSO2C6H4-p-CH3).: Experimental support for an ionic pathway

被引：83

作者：

Aberg, Jenny B. ^{[1
]}

Samec, Joseph S. M. ^{[1
]}

Baeckvall, Jan-E. ^{[1
]}

机构：

[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 26期

关键词：

D O I：

10.1039/b605838h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The need for acidic activation in the stoichiometric hydrogenation of benzyl-[1-phenyl-ethylidene]-amine (6a) or [1-(4-methoxyphenyl)- ethylidene]- methyl-amine (6b) by Noyori's catalyst [p-(Me2CH)C6H4Me] RuH(NH2CHPhCHPhNSO2C6H4-p- CH3) ( 2) is inconsistent with the proposed concerted mechanism and supports an ionic mechanism.

引用

页码：2771 / 2773

页数：3

共 33 条

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