Studies on epoxy-butylated melamine formaldehyde-based anticorrosive coatings from a sustainable resource

被引:23
作者
Ahmad, Sharif [1 ]
Ashraf, S. M. [1 ]
Kumar, G. S. [1 ]
Hasnat, Abul [1 ]
Sharmin, Eram [1 ]
机构
[1] Jamia Millia Islamia, Dept Chem, Mat Res Lab, New Delhi 110025, India
关键词
epoxy; linseed oil; butylated melamine formaldehyde; coatings;
D O I
10.1016/j.porgcoat.2006.05.002
中图分类号
O69 [应用化学];
学科分类号
081704 [应用化学];
摘要
In situ epoxidation of linseed oil (LO) was carried out as per previously reported method. Epoxidised oil (LOE) was further hydroxylated (HLOE) and cured with butylated melamine formaldehyde (BMF), in varying weight percentages (10-30 wt.% on the weight of epoxy resin) to develop coating materials. Structural elucidation of HLOE and HLOE-BMF system was performed by IR, H-1 NMR and C-13 NMR spectroscopic analyses. Physico-chemical characterization was carried out by standard methods. Thermal stability and curing behaviour of these systems were investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), respectively. HLOE-BMF systems were applied over mild steel strips of standard sizes to evaluate their physico-mechanical and chemical resistance performance. It was found that, among all resin compositions, HLOE-30 exhibited far better coating properties. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:207 / 213
页数:7
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