Mono- and dinuclear (o-thioetherphenolato)-copper(II) complexes.: Structural models for galactose oxidase

被引：49

作者：

Kruse, T ^{[1
]}

Weyhermüller, T ^{[1
]}

Wieghardt, K ^{[1
]}

机构：

[1] Max Planck Inst Strahlenchem, D-45470 Mulheim, Germany

来源：

INORGANICA CHIMICA ACTA | 2002年 / 331卷

关键词：

o-thioetherphenols; copper cornplexes; galactose oxidase models; magnetochemistry;

D O I：

10.1016/S0020-1693(01)00756-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new o-thioetherphenol ligands have been synthesized: 1,2-bis(3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)ethane (H(2)bse), 1,2-bis (3,5-di-tert-butyl-2-hydroxyphenylsulfanyl)benzene (H(2)bsb), and 4,6-di-tert-butyl-2-phenylsulfanylphenol (Hpsp). Their complexes with copper(II) were prepared and investigated by UV-Vis-, EPR-spectroscopy, their electro- and magnetochemistry have also been studied: [Cu-II(psp)(2)] (1). [Cu-2(II)(bse)(2)] (2), [Cu-2(II)(bsb)(2)] (3), [Cu-II(bsb)(py)(2)] (4). The crystal structures of the ligands H(2)bse, H(2)bsb, Hpsp and of the complexes 1, 2, 3, 4 have been determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：81 / 89

页数：9

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