To achieve stable spherical clusters: General principles and experimental confirmations

被引：109

作者：

Chen, Zhongfang ^{[1
]}

Neukermans, Sven

Wang, Xin

Janssens, Ewald

Zhou, Zhen

Silverans, Roger E.

King, R. Bruce

Schleyer, Paul von Rague

Lievens, Peter

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

[2] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA

[3] Katholieke Univ Leuven, Lab Vaste Stoffys Magnetisme, B-3001 Heverlee, Belgium

[4] Nankai Univ, Inst Comp Sci, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 39期

关键词：

INDEPENDENT CHEMICAL-SHIFTS; CONSISTENT PERTURBATION-THEORY; METAL-CLUSTERS; CAGED CLUSTERS; ZINTL IONS; GAS ATOMS; AROMATICITY; FULLERENES; SN; GE;

D O I：

10.1021/ja062868g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

General principles for designing stable highly symmetrical clusters are proposed. This approach takes advantage of both the extra stability of cage aromaticity and the good geometrical balance between the outer cage and the endohedral atom. The applicability of these design principles was confirmed by gas-phase experimental observations on group 14 element cages with endohedral Al's and also is illustrated by many literature examples of diverse systems.

引用

页码：12829 / 12834

页数：6

共 88 条

[1] [Anonymous], 2002, Endofullerenes: A New Family of Carbon Clusters
[2] Production of bimetallic clusters by a dual-target dual-laser vaporization source
Bouwen, W
Thoen, P
Vanhoutte, F
Bouckaert, S
Despa, F
Weidele, H
Silverans, RE
Lievens, P
[J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (01) : 54 - 58
[3] SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF THE CENTERED ICOSAHEDRAL GOLD CLUSTER COMPOUND [AU13(PME2PH)10CL2](PF6)3 - THE REALIZATION OF A THEORETICAL PREDICTION
BRIANT, CE
THEOBALD, BRC
WHITE, JW
BELL, LK
MINGOS, DMP
WELCH, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (05) : 201 - 202
[4] Evidence of hollow golden cages
Bulusu, Satya
Li, Xi
Wang, Lai-Sheng
Zeng, Xiao Cheng
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (22) : 8326 - 8330
[5] Special stability of cationic MPb12+ clusters and superalkali character of neutral MPb12 clusters (M=B, Al, Ga, In, and Tl)
Chen, DL
Tian, WQ
Lu, WC
Sun, CC
[J]. JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (15)
[6] Spherical aromaticity: Recent work on fullerenes, polyhedral boranes, and related structures
Chen, ZF
King, RB
[J]. CHEMICAL REVIEWS, 2005, 105 (10) : 3613 - 3642
[7] Nucleus-independent chemical shifts (NICS) as an aromaticity criterion
Chen, ZF
Wannere, CS
Corminboeuf, C
Puchta, R
Schleyer, PV
[J]. CHEMICAL REVIEWS, 2005, 105 (10) : 3842 - 3888
[8] Spherical sila- and germa-homoaromaticity
Chen, ZF
Hirsch, A
Nagase, S
Thiel, W
Schleyer, PV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (50) : 15507 - 15511
[9] Chen ZF, 2002, ANGEW CHEM INT EDIT, V41, P4309, DOI 10.1002/1521-3773(20021115)41:22<4309::AID-ANIE4309>3.0.CO
[10] 2-E

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