Efficient syntheses of L-ribose and 2-deoxy L-ribose from D-ribose and L-arabinose

被引：52

作者：

Jung, ME

Xu, Y

机构：

[1] Dept. of Chemistry and Biochemistry, University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(97)00870-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Interconversion of the ends of D-ribose 2 afforded in 6 steps and 45% overall yield L-ribose 1, from which 2-deoxy L-ribose 12 was easily prepared. In addition, the inexpensive L-arabinose 13 was also converted into 2-deoxy L-ribose 12 via a reductive radical rearrangement of the arabinopyranosyl bromide 14. (C) 1997 Elsevier Science Ltd.

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页码：4199 / 4202

页数：4

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