Synthesis and structural characterization of palladium(II) and platinum(II) complexes containing a chiral P,N-donor iminophosphine ligand

被引：16

作者：

Song, HB

Zhang, ZZ

Mak, TCW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

POLYHEDRON | 2002年 / 21卷 / 9-10期

关键词：

palladium complexes; platinum complexes; chiral iminophosphine ligand;

D O I：

10.1016/S0277-5387(02)00914-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new chiral P,N-donor iminophosphine ligand was used to synthesize a series of palladium(II) and platinum(II) complexes. Single crystal X-ray analysis showed that in all cases the P,N ligand forms a six-membered chelate ring, and the square-planar coordination of the metal atom is completed by two halide ions, two methyl groups, or one methyl group and one halide ion. In the latter instance, the methyl group is cis to the phosphorus atom. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：1043 / 1050

页数：8

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