Expanding and shrinking porous modulation based on pillared-layer coordination polymers showing selective guest adsorption

被引：379

作者：

Maji, TK ^{[1
]}

Uemura, K ^{[1
]}

Chang, HC ^{[1
]}

Matsuda, R ^{[1
]}

Kitagawa, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 25期

关键词：

adsorption; cadmium; coordination polymers; host-guest systems; microporous materials;

D O I：

10.1002/anie.200453923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rationally designed and synthesized, two novel pillar-layered 3D microporous frameworks {[Cd(pzdc)(azpy)]·2H2O}n, (1, left) and {[Cd(pzdc)(bpee)]·1.5H2O}n, (2, right) have high thermal stability and highly selective adsorption properties. Removal of guest water molecules results in the expansion of 1 but the contraction of 2.

引用

页码：3269 / 3272

页数：4

共 34 条

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