Nickel/zinc-mediated synthesis of aromatic nitriles from aromatic oxime ethers

被引：14

作者：

Maeyama, K ^{[1
]}

Kobayashi, M ^{[1
]}

Kato, H ^{[1
]}

Yonezawa, N ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Organ & Polymer mat, Koganei, Tokyo 1848588, Japan

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 16期

关键词：

aromatic oxime ether; aromatic nitriles; nickel/zinc reagent;

D O I：

10.1081/SCC-120005932

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of o-alkoxybenzaldoxime ethers 3 with an equimolar amount of NiCl2 and 3 equimolar amounts of Zn gave o-alkoxybenzonitrites 4 in good yields. It is suggested that the reaction proceed via coordination of the ether oxygen atom of alkyl ether moiety to low-valent metal species.

引用

页码：2519 / 2525

页数：7

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