A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine

被引：57

作者：

Schmid, L ^{[1
]}

Rohr, M ^{[1
]}

Baiker, A ^{[1
]}

机构：

[1] ETH Zentrum, Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a906956i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mesoporous ruthenium silica hybrid aerogel containing well dispersed bidentate RuCl2[Ph2P(CH2)(3)PPh2](2) complexes, synthesized using a sol-gel method, affords turnover frequencies up to 18400 h(-1) and 100% selectivity from CO2, H-2 and diethylamine for the formation of N,N-diethylformamide.

引用

页码：2303 / 2304

页数：2

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