Metallodendrimers containing both ruthenium (internal layer) and rhenium (external layer)

被引：12

作者：

Angurell, Inma

Lima, Joao C.

Rodriguez, Lara-Isabel

Rodriguez, Laura

Rossell, Oriol

Seco, Miquel

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Univ Nova Lisboa, REQUIMTE, Ctr Quim Fina & Biotecnol, Dept Quim, P-2829516 Monte De Caparica, Portugal

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 07期

关键词：

D O I：

10.1039/b518356a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Re(bipy)(CO)(3)(C=Cpy)] with two carbosilane dendrimers containing terminal (p-cymene)Ru(triflate)(2) units gives bimetallic dendrimers functionalised with (p-cymene) Ru(triflate)(pyC=C)Re(bipy)(CO)(3) units. Dendrimers of this kind can be envisaged as formed by two metal layers: the internal, constituted by ruthenium atoms, and the external, by rhenium metals. The luminescent properties of these species are only attributed to the rhenium moieties.

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页码：1004 / 1008

页数：5

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