Transmission electron microscopy investigation of fullerene nanowhiskers and needle-like precipitates formed by using C60 and (η2-C60)Pt(PPh3)2

被引：22

作者：

Miyazawa, K

Suga, T

机构：

[1] Natl Inst Mat Sci, Ecomat Ctr, Tsukuba, Ibaraki 3050044, Japan

[2] Univ Tokyo, Sch Engn, Dept Precis Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF MATERIALS RESEARCH | 2004年 / 19卷 / 08期

关键词：

D O I：

10.1557/JMR.2004.0304

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanowhiskers and needle-like precipitates obtained by the liquid-liquid interfacial precipitation method for the systems of isopropyl alcohol and toluene solutions of C-60 and (eta(2)-C-60)Pt(PPh3)(2) were examined by transmission electron microscopy. Morphology of the C-60 precipitates was remarkably changed by the addition of (eta(2)-C-60)Pt(PPh3)(2) in the C-60 toluene solution, and capsular needle-like crystals of C-60 were formed. C-60 cages were found to be directly contacted along the growth axis of (eta(2)-C-60)Pt(PPh3)(2) needle-like crystals.

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页码：2410 / 2414

页数：5

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