Versatile chain transfer agents for reversible addition fragmentation chain transfer (RAFT) polymerization to synthesize functional polymeric architectures

被引：180

作者：

Perrier, S ^{[1
]}

Takolpuckdee, P ^{[1
]}

Westwood, J ^{[1
]}

Lewis, DM ^{[1
]}

机构：

[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

MACROMOLECULES | 2004年 / 37卷 / 08期

关键词：

D O I：

10.1021/ma035468b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the syntheses and uses of versatile chain transfer agents (CTAs) that produce well-controlled macromolecular architectures with specific chain-end functionalities, via reversible addition fragmentation chain transfer (RAFT) polymerization). Examples of architectures are given, including amphiphilic copolymers and block copolymers incorporating a biodegradable block. These CTAs are also used for the grafting of poly(styrene), poly(methyl methacrylate) and poly(methyl acrylate) from cotton.

引用

页码：2709 / 2717

页数：9

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