The synthesis of alpha-monofluorovinylphosphonates by a Peterson type olefination reaction

被引：15

作者：

Keeney, A ^{[1
]}

Nieschalk, J ^{[1
]}

OHagan, D ^{[1
]}

机构：

[1] DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 80卷 / 01期

关键词：

synthesis; alpha-monofluorovinylphosphonates; Peterson olefination; F-19-; H-1 and P-31-NMR spectroscopy;

D O I：

10.1016/S0022-1139(96)03460-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of alpha-lithium-alpha-fluoro-alpha-trimethylsilyl-methylphosphonate 2 with aldehydes 3a-fleads to alpha-fluorovinylphosphonates 4a-fby a Peterson type olefination reaction.

引用

页码：59 / 62

页数：4

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