Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study

被引:61
作者
Lyapustina, SA [1 ]
Xu, SK [1 ]
Nilles, JM [1 ]
Bowen, KH [1 ]
机构
[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
关键词
D O I
10.1063/1.481237
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that (a) only a single water molecule is needed to stabilize the naphthalene anion, (b) the EA(a) of naphthalene is -0.20 eV, in agreement with determinations by electron transmission spectroscopy, (c) the energetics are consistent with the number of waters required to stabilize the naphthalene anion, and (d) the excess electron is located on the naphthalene moiety of Nph(1)(-)(H2O)(n). (C) 2000 American Institute of Physics. [S0021-9606(00)00915-6].
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收藏
页码:6643 / 6648
页数:6
相关论文
共 46 条
[1]   Non-covalent binary interactions between some organic acids and bases [J].
Abdoul-Carime, H ;
Wakisaka, A ;
Flugge, J ;
Takeo, H ;
Periquet, V ;
Schermann, JP ;
Desfrancois, C .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (24) :4289-4293
[2]   Electron attachment energies of the DNA bases [J].
Aflatooni, K ;
Gallup, GA ;
Burrow, PD .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (31) :6205-6207
[3]  
AFLATOONI K, UNPUB
[4]  
BALK P, 1957, RECL TRAV CHIM PAY B, V76, P813
[5]   ELECTRON TRANSMISSION STUDY OF THE TEMPORARY NEGATIVE-ION STATES OF SELECTED BENZENOID AND CONJUGATED AROMATIC-HYDROCARBONS [J].
BURROW, PD ;
MICHEJDA, JA ;
JORDAN, KD .
JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (01) :9-24
[6]   TEMPORARY ANION STATES OF PHOSPHABENZENE, ARSABENZENE, AND STIBABENZENE - TRENDS IN THE PI AND PI-STAR ORBITAL ENERGIES [J].
BURROW, PD ;
ASHE, AJ ;
BELLVILLE, DJ ;
JORDAN, KD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) :425-429
[7]   EXPERIMENTAL-STUDY OF NEGATIVE-ION STATES OF STYRENE - TEST OF PAIRING THEOREM [J].
BURROW, PD ;
MICHEJDA, JA ;
JORDAN, KD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (20) :6392-6393
[8]   UNSTABLE INTERMEDIATES .4. ELECTRON SPIN RESONANCE STUDIES OF UNIVALENT AROMATIC HYDROCARBON IONS [J].
CARRINGTON, A ;
DRAVNIEKS, F ;
SYMONS, MCR .
JOURNAL OF THE CHEMICAL SOCIETY, 1959, (MAR) :947-952
[9]  
CARRINGTON A, 1979, INTRO MAGNETIC RESON, P72
[10]   PHOTOELECTRON-SPECTROSCOPY OF THE NEGATIVE-ION SEO- [J].
COE, JV ;
SNODGRASS, JT ;
FREIDHOFF, CB ;
MCHUGH, KM ;
BOWEN, KH .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (02) :618-625