Simple synthesis, outstanding thermal stability, and tunable light-emitting and optical-limiting properties of functional hyperbranched polyarylenes

被引:87
作者
Peng, H
Cheng, L
Luo, JD
Xu, KT
Sun, QH
Dong, YP
Salhi, F
Lee, PPS
Chen, JW
Tang, BZ
机构
[1] Hong Kong Univ Sci & Technol, Dept Chem, Ctr Display Res, Inst Nano Sci & Technol, Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Univ Sci & Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synthesis, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Univ Sci & Technol, Kowloon, Hong Kong, Peoples R China
关键词
D O I
10.1021/ma020180s
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis, thermal stability and optical properties of functional hyperbranched polyarylenes were reported. The molecular structure of the polymers was determined by nuclear magnetic resonance (NMR) spectroscopy. The spectra showed that the hyperbranched polymers possessed a random molecular composition, an irregular stereostructure and a rigid core architecture. The optical limiting and tunable light emitting properties of the polymers make them suitable to be used for high-tech applications.
引用
收藏
页码:5349 / 5351
页数:3
相关论文
共 31 条
[1]  
[Anonymous], 1886, MONATSH, DOI [DOI 10.1007/BF01516557, 10.1007/BF01516557]
[2]  
Brandsma L., 1981, Synthesis of Acetylenes, Allenes, Cumulenes: A Laboratory Manual
[3]   An alternative synthetic approach toward dendritic macromolecules:: Novel benzene-core dendrimers via alkyne cyclotrimerization [J].
Hecht, S ;
Fréchet, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (16) :4084-4085
[4]   Strong photoluminescence from monosubstituted polyacetylenes containing biphenylyl chromophores [J].
Huang, YM ;
Ge, WK ;
Lam, JWY ;
Tang, BZ .
APPLIED PHYSICS LETTERS, 1999, 75 (26) :4094-4096
[5]   Influence of electric field on the photoluminescence of a liquid crystalline monosubstituted polyacetylene [J].
Huang, YM ;
Ge, WK ;
Lam, JWY ;
Tang, BZ .
APPLIED PHYSICS LETTERS, 2001, 78 (12) :1652-1654
[6]  
JOHNEN NA, 1994, ACS SYM SER, V579, P298
[7]   HYPERBRANCHED POLYPHENYLENES [J].
KIM, YH ;
WEBSTER, OW .
MACROMOLECULES, 1992, 25 (21) :5561-5572
[8]  
Kim YH, 1998, J POLYM SCI POL CHEM, V36, P1685, DOI 10.1002/(SICI)1099-0518(199808)36:11<1685::AID-POLA1>3.3.CO
[9]  
2-4
[10]   Synthesis and novel mesomorphic properties of the side-chain liquid crystalline polyacetylenes containing phenyl benzoate mesogens with cyano and methoxy tails [J].
Kong, XX ;
Tang, BZ .
CHEMISTRY OF MATERIALS, 1998, 10 (11) :3352-3363