Tuning current rectification across molecular junctions

被引:74
作者
Kushmerick, JG [1 ]
Whitaker, CM
Pollack, SK
Schull, TL
Shashidhar, R
机构
[1] USN, Res Lab, Ctr Biomol Sci & Engn, Washington, DC 20375 USA
[2] USN Acad, Dept Chem, Annapolis, MD 21402 USA
关键词
D O I
10.1088/0957-4484/15/7/058
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We demonstrate the ability to tune the current rectification in metal-molecule-metal junctions through control of the interaction strength of one of the two metal-molecule contacts. Current-voltage characteristics of thiolate bound molecular wires with a nitro or pyridine termination show that the extent of current rectification in a molecular junction correlates well with the extent of coupling between the chemical linker and metal electrode.
引用
收藏
页码:S489 / S493
页数:5
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