Synthesis of molybdenum disulfide (MoS2) for lithium ion battery applications

被引：370

作者：

Feng, Chuanqi ^{[1
,2
]}

Ma, Jun ^{[2
]}

Li, Hua ^{[2
]}

Zeng, Rong ^{[1
]}

Guo, Zaiping ^{[1
,3
,4
]}

Liu, Huakun ^{[1
,4
]}

机构：

[1] Univ Wollongong, Inst Supercond & Elect Mat, Wollongong, NSW 2522, Australia

[2] Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China

[3] Univ Wollongong, Sch Mech Mat & Mechatron Engn, Wollongong, NSW 2522, Australia

[4] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 09期

基金：

澳大利亚研究理事会;

关键词：

Inorganic compounds; Layered compounds; Nanostructures; Chemical synthesis; Electrochemical properties; NANOTUBES; WS2; NANOSTRUCTURES; STORAGE; ROUTE; FILMS;

D O I：

10.1016/j.materresbull.2009.05.018

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This paper reports the use of a theological phase reaction method for preparing MoS2 nanoflakes. The characterization by powder X-ray diffraction indicated that MoS2 had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS2 nanoflakes had started to curve and partly form MoS2 nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS2 nanoflake electrode was also investigated. It was found that the MoS2 nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS2 nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS2 nanoflakes obtained by this method make it possible for MoS2 to be used as a promising anode material. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1811 / 1815

页数：5

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