Catalyst control in a chiral borane-mediated aldol reaction. Both syn- and anti-aldols in almost optically pure state obtained from one racemic aldehyde

被引:39
作者
Kiyooka, S
Kira, H
Hena, MA
机构
[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
关键词
D O I
10.1016/0040-4039(96)00379-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chiral borane (L-2 and D-2)-mediated aldol reaction proceeded with chiral aldehydes (1, 5, and 9) in a manner of ''catalyst control''. Both enantiomers were obtained from one racemic aldehyde in almost optically pure state. Copyright (C) 1996 Elsevier Science Ltd
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页码:2597 / 2600
页数:4
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