Catalyst control in a chiral borane-mediated aldol reaction. Both syn- and anti-aldols in almost optically pure state obtained from one racemic aldehyde
被引:39
作者:
Kiyooka, S
论文数: 0引用数: 0
h-index: 0
机构:Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
Kiyooka, S
Kira, H
论文数: 0引用数: 0
h-index: 0
机构:Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
Kira, H
Hena, MA
论文数: 0引用数: 0
h-index: 0
机构:Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
Hena, MA
机构:
[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho
Chiral borane (L-2 and D-2)-mediated aldol reaction proceeded with chiral aldehydes (1, 5, and 9) in a manner of ''catalyst control''. Both enantiomers were obtained from one racemic aldehyde in almost optically pure state. Copyright (C) 1996 Elsevier Science Ltd