Catalyst control in a chiral borane-mediated aldol reaction. Both syn- and anti-aldols in almost optically pure state obtained from one racemic aldehyde

被引：39

作者：

Kiyooka, S

Kira, H

Hena, MA

机构：

[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi 780, Akebono-cho

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 15期

关键词：

D O I：

10.1016/0040-4039(96)00379-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral borane (L-2 and D-2)-mediated aldol reaction proceeded with chiral aldehydes (1, 5, and 9) in a manner of ''catalyst control''. Both enantiomers were obtained from one racemic aldehyde in almost optically pure state. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2597 / 2600

页数：4

共 26 条

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