A novel synthetic route to pentaalkylcyclopentadienylgallium(I) compounds

被引：68

作者：

Jutzi, P ^{[1
]}

Schebaum, LO ^{[1
]}

机构：

[1] Univ Bielefeld, Fac Chem Anorgan Chem 3, D-33615 Bielefeld, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 654卷 / 1-2期

关键词：

gallium; green's GaI; Me5C5Ga; Me4EtC5Ga;

D O I：

10.1016/S0022-328X(02)01429-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 'GaI' with potassium cyclopentadienides allows a simple access to cyclopentadienylgallium(I)-complexes. Thus, the compounds Me5C5Ga 1 and Me4EtC5Ga 2 have been prepared in high yields. Performing the synthesis of 'GaI' under ultrasonic conditions not in toluene but in benzene as solvent, avoids the formation of benzyl iodide as side product. (C) 2002 Published by Elsevier Science B.V.

引用

页码：176 / 179

页数：4

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