Design of novel magnets using Prussian blue analogues

被引:107
作者
Hashimoto, K [1 ]
Ohkoshi, S [1 ]
机构
[1] Univ Tokyo, Res Ctr Adv Sci & Technol, Meguro Ku, Tokyo 1538904, Japan
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1999年 / 357卷 / 1762期
关键词
molecule-based magnet; Prussian blue; photomagnet; pole inversion; molecular field theory; supercharge interaction;
D O I
10.1098/rsta.1999.0477
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The main aim of this paper is to show how well we can design novel molecule-based magnets using Prussian blue analogues based on theory. We obtained various novel magnets, i.e. magnets containing both ferro- and antiferromagnetic interactions without spin frustration, a magnet having two compensation temperatures, coloured transparent magnets, a photomagnet and a photoinduced pole inversion magnet. These magnets were designed using simple theories, including molecular field theory.
引用
收藏
页码:2977 / 3003
页数:27
相关论文
共 32 条
[1]  
ANDERSON EE, 1964, P INT C MAGNETISM NO, P660
[2]   NEW APPROACH TO THE THEORY OF SUPEREXCHANGE INTERACTIONS [J].
ANDERSON, PW .
PHYSICAL REVIEW, 1959, 115 (01) :2-13
[3]   Electronic states of cobalt iron cyanides studied by Fe-57 Mossbauer spectroscopy [J].
Einaga, Y ;
Sato, O ;
Iyoda, T ;
Kobayashi, Y ;
Ambe, F ;
Hashimoto, K ;
Fujishima, A .
CHEMISTRY LETTERS, 1997, (04) :289-290
[4]   NEW 3-DIMENSIONAL FERRIMAGNETIC MATERIALS - K2MN[MN(CN)(6)], MN-3[MN(CN)(6)]CENTER-DOT(2)12H2O, AND CSMN[MN(CN)(6)]CENTER-DOT-1/2H2O [J].
ENTLEY, WR ;
GIROLAMI, GS .
INORGANIC CHEMISTRY, 1994, 33 (23) :5165-5166
[5]   A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].
FERLAY, S ;
MALLAH, T ;
OUAHES, R ;
VEILLET, P ;
VERDAGUER, M .
NATURE, 1995, 378 (6558) :701-703
[6]  
Gatteschi D., 1991, NATO ASI SERIES E, VE198
[7]  
GINSBERG AP, 1971, INORG CHIM ACTA REV, V5, P45, DOI DOI 10.1016/0073-8085(71)80012-8
[9]   THEORY OF THE ROLE OF COVALENCE IN THE PEROVSKITE-TYPE MANGANITES [LA,M(II)]MNO3 [J].
GOODENOUGH, JB .
PHYSICAL REVIEW, 1955, 100 (02) :564-573
[10]  
GORTER EW, 1954, PHILIPS RES REP, V9, P295