Design of novel magnets using Prussian blue analogues

被引:107
作者
Hashimoto, K [1 ]
Ohkoshi, S [1 ]
机构
[1] Univ Tokyo, Res Ctr Adv Sci & Technol, Meguro Ku, Tokyo 1538904, Japan
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1999年 / 357卷 / 1762期
关键词
molecule-based magnet; Prussian blue; photomagnet; pole inversion; molecular field theory; supercharge interaction;
D O I
10.1098/rsta.1999.0477
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The main aim of this paper is to show how well we can design novel molecule-based magnets using Prussian blue analogues based on theory. We obtained various novel magnets, i.e. magnets containing both ferro- and antiferromagnetic interactions without spin frustration, a magnet having two compensation temperatures, coloured transparent magnets, a photomagnet and a photoinduced pole inversion magnet. These magnets were designed using simple theories, including molecular field theory.
引用
收藏
页码:2977 / 3003
页数:27
相关论文
共 32 条
[11]  
GRIEBLER WD, 1982, Z NATURFORSCH B, V87, P832
[12]  
Hush N.S., 1967, PROG INORG CHEM, V8, P391, DOI DOI 10.1002/9780470166093.CH7
[13]  
Kahn O, 1993, MOL MAGNETISM
[15]  
Ludi A., 1973, Structure and Bonding, V14, P1, DOI 10.1007/bfb0016869
[16]   MOLECULAR-BASED MIXED-VALENCY FERRIMAGNETS (XR(4))(FEIIFEIII)(C2O4)(3) (X=N, P, R=N-PROPYL, N-BUTYL, PHENYL) - ANOMALOUS NEGATIVE MAGNETIZATION IN THE TETRA-N-BUTYLAMMONIUM DERIVATIVE [J].
MATHONIERE, C ;
CARLING, SG ;
DOU, YS ;
DAY, P .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (13) :1551-1552
[17]   ORGANIC AND ORGANOMETALLIC MOLECULAR MAGNETIC-MATERIALS - DESIGNER MAGNETS [J].
MILLER, JS ;
EPSTEIN, AJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (04) :385-415
[18]  
NEEL L, 1948, ANN PHYS-PARIS, V3, P137
[19]   Theoretical studies on magnetic interactions in Prussian blue analogs and active controls of spin states by external fields. [J].
Nishino, M ;
Kubo, S ;
Yoshioka, Y ;
Nakamura, A ;
Yamaguchi, K .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 305 :109-128
[20]   Magnetic properties and optical control of electrochemically prepared iron-chromium polycyanides [J].
Ohkoshi, S ;
Einaga, Y ;
Fujishima, A ;
Hashimoto, K .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 473 (1-2) :245-249