Calix[4]arene-functionalized naphthalene and perylene imide dyes

被引:29
作者
Vysotsky, MO
Böhmer, V
Wurthner, F
You, CC
Rissanen, K
机构
[1] Univ Mainz, Abt Lehramt Chem, Fachbereich Chem & Pharm, D-55099 Mainz, Germany
[2] Univ Ulm, Abt Organ Chem 2, D-89081 Ulm, Germany
[3] Univ Jyvaskyla, Dept Chem, FIN-40351 Jyvaskyla, Finland
关键词
D O I
10.1021/ol026402o
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHIC] Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C-2-symmetrical pinched cone conformation stabilized via face-to-face pi-pi interactions between opposite naphthylimide groups. UV-vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes.
引用
收藏
页码:2901 / 2904
页数:4
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