Preparation and application of a polymer-supported chiral π-allylpalladium catalyst for the allylation of imines

被引：50

作者：

Bao, M ^{[1
]}

Nakamura, H ^{[1
]}

Yamamoto, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 01期

关键词：

polymer support; palladium catalyst; imines; catalytic asymmetric allylation;

D O I：

10.1016/S0040-4039(99)02032-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The polymer-supported chiral pi-allylpalladium catalyst 8 was applied to the asymmetric allylation reaction of imines 9 with allyltributylstannane. The catalyst was very stable and could be reused several times with high catalytic activity, although the enantioselectivity was not necessarily high. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：131 / 134

页数：4

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