The Pd(II) complex of a bidentate di(benzimidazol-2-ylidene) ligand

被引：28

作者：

Hahn, FE

von Fehren, T

Wittenbecher, L

Fröhlich, R

机构：

[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2004年 / 59卷 / 05期

关键词：

carbene ligand; palladium(II); crystal structure;

D O I：

10.1515/znb-2004-0509

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pale yellow palladium(II) dicarbene complex cis-[PdI2(L)], 2 (L = 1,3-bis-(3-neopentylbenzimidazol-2-ylidene)-2,2-dimethylpropane) was synthesized by the reaction of PdI2 with an N1,N1'-2,2'-dimethylpropane-bridged dibenzotetraazafulvalene 1 in tetrahydrofuran. The X-ray structure analysis revealed a mononuclear complex with a palladium(II) center coordinated in a slightly distorted square-planar fashion by the bidentate carbene ligand and two iodo ligands.

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页码：541 / 543

页数：3

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