Lithium-ion rechargeable cells with polyacenic semiconductor (PAS) and LiCoO2 electrodes

被引：5

作者：

Huang, BY ^{[1
]}

Xue, RJ ^{[1
]}

Li, GB ^{[1
]}

Huang, YZ ^{[1
]}

Yan, HW ^{[1
]}

Chen, LQ ^{[1
]}

Wang, FS ^{[1
]}

机构：

[1] CHINESE ACAD SCI,BEIJING 1000864,PEOPLES R CHINA

来源：

JOURNAL OF POWER SOURCES | 1996年 / 58卷 / 02期

关键词：

lithium-ion batteries; rechargeable lithium cells; polyacenic semiconductor; lithium; electrodes;

D O I：

10.1016/0378-7753(96)89189-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polyacenic semiconductor (PAS), heat-treated at 700 degrees C, has a lithium intercalation capacity as high as 438 mAh g(-1) which is higher than the theoretical capacity of 372 mAh g(-1) for graphite. The electrochemical behaviour of PAS is examined by studying Li/PAS and Li/graphite cells. In a PAS or graphite anode, three reactions are distinguished: (i) reaction of lithium with the Teflon binder; () decomposition of electrolyte, and (iii) intercalation of Li+ ions. Two laboratory cells with liquid organic electrolyte or polymer electrolyte and PAS as the anode demonstrate that PAS is a promising anode material for lithium-ion batteries.

引用

页码：177 / 181

页数：5

共 11 条

[1] IDENTIFICATION OF SURFACE-FILMS FORMED ON LITHIUM IN PROPYLENE CARBONATE SOLUTIONS [J].