Reactions of platinum(II)-nitrile complexes with amines.: Synthesis, characterization and X-ray structure of the platinum (II)-amidine complex trans-[PtCl2{Z-N(H)=C(NHMe)Me}2]

被引：42

作者：

Bertani, R

Catanese, D

Michelin, RA

Mozzon, M

Bandoli, G

Dolmella, A

机构：

[1] Univ Padua, CNR, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

[2] Univ Padua, CNR, Ctr Studio Chim & Tecnol Composti Met Organ Eleme, I-35131 Padua, Italy

[3] Univ Padua, Dipartimento Sci Farmaceut, I-35131 Padua, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 01期

关键词：

platinum complexes; nitrile complexes; amidine complexes; crystal structures;

D O I：

10.1016/S1387-7003(99)00174-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of trans-[PtCl2(NCMe)(2)] with a 5-fold excess of MeNH2 in CH2Cl2 at -10 degrees C affords in high yield the bis-amidine complex trans-[PtCl2{Z-N(H) = C(NHMe)Me}(2)] (1),where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the C = N triple band. Compound I has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis. (C) 2000 Elsevier Science S.A. All rights reserved.

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收藏

页码：16 / 18

页数：3

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