Nucleophilic addition reactions to the allenylidene complex [CpRu=C=C=CPh2(CO)(PMeiPr2)]+:: X-ray crystal structures of [CpRu{C(N=CPh2)CH=CPh2}(CO) (PMeiPr2)][BAr′4],[CpRu{C(NHCH2C≡CH)CH-CPh2}(CO)(PMeiOr2)][BAr′4],[CpRu{C(PMeiPr2)C=CPh2}(CO)(PMeiPr2)][BA′4] and [Cp*Ru{C(SnPr)CH=CPh2}(CO)(PMeiPr2)][BAr′4]

被引：25

作者：

Jiménez-Tenorio, M ^{[1
]}

Palacios, MD ^{[1
]}

Puerta, MC ^{[1
]}

Valerga, P ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias Mar, Dept Ciencias Mat & Ingn Met & Quim Inorgan, E-11510 Puerto Real, Cadiz, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 17期

关键词：

allenylidene; azaallenyl; azoniabutadienyl; thiocarbene;

D O I：

10.1016/j.jorganchem.2004.06.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The allenylidene complex [Cp* Ru=C=C=CPh2(CO)(PMe'Pr-2)[BAr'(4)] (1) reacts with benzophenoneimine yielding the azaallenyl derivative [Cp*Ru{C(N=CPh2)CH=CPh2}CO)(PMe'Pr-2)][BAr'(4)] (2). The addition of primary or secondary amines to 1 yields vi- nylaminocarbenes, which are better formulated as azoniabutadienyl complexes [Cp*Ru{C(NRR')CH=CPh2}(CO) (PMe'Pr-2)][BAr'(4)] (R=H, R'=CH(2)CdropCH (3), R=H, R'=Me (4), R=R'=Pr (5)). Tertiary phosphines add to the C-alpha atom of 4 the allenylidene chain furnishing allenylphosphonio species [Cp*Ru{C(PR3)C=CPh2}(CO)(PMe'Pr-2)][BAr'(4)] (PR3=PMe3 (6), 4 PMe'Pr-2 (7)). The reaction of 1 with propanethiol afforded the thiocarbene [Cp*Ru{C((SPr)-Pr-n)CH=CPh2}(CO)(PMe'Pr-2)][BAr'(4)] (8), which can be treated as a eta1-thiabutadienyl. (C) 2004 Elsevier B.V. All rights reserved.

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页码：2776 / 2785

页数：10

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