Effect of the temperature of calcination on the catalytic performance of manganese- and samarium-manganese-based oxides in the complete oxidation of acetone

被引:66
作者
Gil, A [1 ]
Gandía, LM [1 ]
Korili, SA [1 ]
机构
[1] Univ Publ Navarra, Edif Los Acebos, Dept Quim Aplicada, E-31006 Pamplona, Spain
关键词
manganese oxide; samarium-manganese oxide; samarium-manganese perovskite; acetone catalytic combustion; VOCs;
D O I
10.1016/j.apcata.2004.07.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of the calcination temperature on manganese-based catalysts used in the complete oxidation of acetone has been studied. The catalysts, containing manganese and samarium and being in bulk oxide form, were prepared in the laboratory and calcined at 673, 823, 1073 and 1273 K. The calcination temperature controls and modifies the type of single manganese oxide present, the development of the perovskite structure of samarium-manganese oxides, and the specific surface area of these materials. A positive effect on the catalyst performance has been observed for the samarium-manganese oxides with respect to the single manganese ones. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:229 / 235
页数:7
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