Facile synthesis of p-tert-butylthiacalix[4]arene by the reaction of p-tert-butylphenol with elemental sulfur in the presence of a base

被引：562

作者：

Kumagai, H ^{[1
]}

Hasegawa, M ^{[1
]}

Miyanari, S ^{[1
]}

Sugawa, Y ^{[1
]}

Sato, Y ^{[1
]}

Hori, T ^{[1
]}

Ueda, S ^{[1
]}

Kamiyama, H ^{[1
]}

Miyano, S ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC ENGN,DEPT BIOCHEM & ENGN,SENDAI,MIYAGI 98077,JAPAN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(97)00792-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

p-tert-Butylthiacalix[4]arene, in which the four methylene bridges of p-tert-butylcalix[4]arene are replaced by sulfide linkages, is conveniently synthesized in a single step (54%) by heating a mixture of p-tert-butylphenol, elemental sulfur S-8, and NaOH in tetraethylene glycol dimethyl ether with concomitant removal of the resulting hydrogen sulfide. (C) 1997 Elsevier Science Ltd.

引用

页码：3971 / 3972

页数：2

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