Synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)1,3,5-triazines

被引：9

作者：

Popov, AV

Shastin, AV ^{[1
]}

Luzina, EL

Pushin, AN

Gavrishova, TN

机构：

[1] Russian Acad Sci, Inst Physiol Act Subst, Chernogolovka 142432, Moscow Region, Russia

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine; 2-(alkylamino)-4,6-bis(nonafluoro-tert-butyl); 1,3,5-triazines; nucleophilic substitution; hindered rotation; NMR; spectra;

D O I：

10.1007/BF02496410

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A procedure was developed for the synthesis of substituted 2-amino-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazines from 2-chloro-4,6-bis(nonafluoro-tert-butyl)-1,3,5-triazine and aliphatic and aromatic amines. The data of F-19 NMR spectroscopy are indicative of the presence of a barrier to internal rotation.

引用

页码：1548 / 1552

页数：5

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