Asymmetric syntheses of (-)-aphanorphine and (-)-eptazocine

被引：39

作者：

Node, M ^{[1
]}

Imazato, H ^{[1
]}

Kurosaki, R ^{[1
]}

Kawano, Y ^{[1
]}

Inoue, T ^{[1
]}

Nishide, K ^{[1
]}

Fuji, K ^{[1
]}

机构：

[1] KYOTO UNIV,INST CHEM RES,UJI,KYOTO 611,JAPAN

来源：

HETEROCYCLES | 1996年 / 42卷 / 02期

关键词：

D O I：

10.3987/COM-95-S88

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formal asymmetric syntheses of (-)-aphanorphine and (-)-eptazocine were done, utilizing asymmetric nitroolefination reaction of alpha-methyl-delta-valerolactone and a new aromatization of Diels-Alder adducts of chiral nitroolefins with the Danishefsky's diene.

引用

收藏

页码：811 / 819

页数：9

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