Photostabilities of novel heptamethine 3H-indolenine cyanine dyes with different N-substituents

被引：87

作者：

Chen, Xiuying ^{[1
]}

Peng, Xiaojun ^{[1
]}

Cui, Aijun ^{[1
]}

Wang, Bingshuai ^{[1
]}

Wang, Li ^{[1
]}

Zhang, Rong ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2006年 / 181卷 / 01期

基金：

中国国家自然科学基金;

关键词：

near-infrared cyanine dye; photostability; fluorescence quantum yield; photobleaching; fluorescence labeling;

D O I：

10.1016/j.jphotochem.2005.11.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel near-infrared (NIR) 3H-indocyanine dyes with different N-substituents were synthesized and tested to make clear the relationship between photophysical properties and structures and develop potential NIR cyanine dyes with high photostability for fluorescent imaging technology. The electron-withdrawing ability of the substituents on N-position of 3H-indolenine strongly affects the photostabilities of the NIR cyanine dyes and introducing of the electron-donating groups is favorable to obtain NIR cyanine dyes with improved photochemical stability. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：79 / 85

页数：7

共 29 条

[1] ABSORPTION AND FLUORESCENCE PROPERTIES OF CYANINE DYES [J].

BENSON, RC ;

KUES, HA .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1977, 22 (04) :379-383

[2] ELECTRON-TRANSFER EVENTS IN SOLUTIONS OF CYANINE DYES [J].

CHEN, CP ;

ZHOU, BM ;

LI, DH ;

XU, GG .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1995, 89 (01) :25-29

[3] Study on the photooxidation of a near-infrared-absorbing benzothiazolone cyanine dye [J].

Chen, P ;

Li, J ;

Qian, ZG ;

Zheng, DS ;

Okasaki, T ;

Hayami, M .

DYES AND PIGMENTS, 1998, 37 (03) :213-222

[4] Structure and solvent effect on the photostability of indolenine cyanine dyes [J].

Chen, P ;

Sun, SQ ;

Hu, YF ;

Qian, ZG ;

Zheng, DS .

DYES AND PIGMENTS, 1999, 41 (03) :227-231

[5]

Chen X, 1996, CHEM J CHINESE U, V17, P1613

[6] Are fluorescence quantum yields so tricky to measure? A demonstration using familiar stationery products [J].

Fery-Forgues, S ;

Lavabre, D .

JOURNAL OF CHEMICAL EDUCATION, 1999, 76 (09) :1260-1264

[7]

Gallaher DL, 1999, ANALYST, V124, P1541, DOI 10.1039/a904541d

[8] Synthesis of novel near-infrared cyanine dyes for metal ion determination [J].

Gorecki, T ;

Patonay, G ;

Strekowski, L ;

Chin, R ;

Salazar, N .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1996, 33 (06) :1871-1876

[9] Photostable cyanine dye beta-cyclodextrin conjugates [J].

Guether, R ;

Reddington, MV .

TETRAHEDRON LETTERS, 1997, 38 (35) :6167-6170

[10] ELECTROCHEMISTRY AND ELECTRONIC-SPECTRA OF CYANINE DYE RADICALS IN ACETONITRILE [J].

LENHARD, JR ;

CAMERON, AD .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (19) :4916-4925

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