Stereoselectivity in cyclic and acyclic metathesis reactions

被引：12

作者：

Basset, JM ^{[1
]}

Leconte, M ^{[1
]}

Lefebvre, F ^{[1
]}

Hamilton, JG ^{[1
]}

Rooney, JJ ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 11期

关键词：

D O I：

10.1002/macp.1997.021981114

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Metathesis polymers of norbornene and 1-methylnorbornene were prepared using a well-defined aryloxy(chloro)neopentylidene tungsten initiator which behaves in a stereo and regioselective manner giving predominantly cis polymers and a strong head-to-tail bias in the case of 1-methylnorbornene. This is in accord with the observation that this initiator is also very stereoselective in acyclic metathesis.

引用

页码：3499 / 3506

页数：8

共 15 条

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