Selective enzymatic epoxidation of dienes: generation of functional enantiomerically enriched diene monoepoxy monomers

被引：10

作者：

Hu, SH

Gupta, P

Prasad, AK

Gross, RA

Parmar, VS

机构：

[1] Polytech Univ, Dept Chem, NSF, Ctr Biocatalysis & Bioproc Macromol, Brooklyn, NY 11201 USA

[2] Univ Delhi, Dept Chem, Bioorgan Lab, Delhi 110007, India

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 38期

关键词：

enzymatic epoxidation; Pseudomonas putida; Caldariomyces fumago; chloroperoxidase; diene monoepoxide; enantioselective;

D O I：

10.1016/S0040-4039(02)01519-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomerically enriched diene monoepoxides were selectively synthesized using oxidases from Pseudomonas sp. and chloroperoxidase from Caldariomyces fumago. These monoepoxides are useful monomers for generating functional chiral polymeric materials. (C) 2002 Elsevier Science Ltd. All rights reserved.

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收藏

页码：6763 / 6766

页数：4

相关论文

共 31 条

[1] HIGHLY ENANTIOSELECTIVE EPOXIDATION OF DISUBSTITUTED ALKENES WITH HYDROGEN-PEROXIDE CATALYZED BY CHLOROPEROXIDASE [J].

ALLAIN, EJ ;

HAGER, LP ;

DENG, L ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4415-4416

[2]

Bentley PA, 1997, CHIRALITY, V9, P198, DOI 10.1002/(SICI)1520-636X(1997)9:2<198::AID-CHIR22>3.0.CO

[3]

2-H

[4] Asymmetric epoxidation of enones employing polymeric alpha-amino acids in non-aqueous media [J].

Bentley, PA ;

Bergeron, S ;

Cappi, MW ;

Hibbs, DE ;

Hursthouse, MB ;

Nugent, TC ;

Pulido, R ;

Roberts, SM ;

Wu, LE .

CHEMICAL COMMUNICATIONS, 1997, (08) :739-740

[5] CHROMATOGRAPHIC RESOLUTION OF RACEMATES [J].

BLASCHKE, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (01) :13-24

[6] Synthesis of well-defined poly(methyl methacrylate) by radical polymerization with a new initiation system TPED/FeCl3/PPh3 [J].

Chen, XP ;

Qiu, KY .

MACROMOLECULES, 1999, 32 (26) :8711-8715

[7] DIMETHYLOXOSULFONIUM METHYLIDE ((CH3)2SOCH2) AND DIMETHYLSULFONIUM METHYLIDE ((CH3)2SCH2) FORMATION AND APPLICATION TO ORGANIC SYNTHESIS [J].

COREY, EJ ;

CHAYKOVSKY, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1353-+

[8] HIGHLY ENANTIOSELECTIVE EPOXIDATION OF 1,1-DISUBSTITUTED ALKENES CATALYZED BY CHLOROPEROXIDASE [J].

DEXTER, AF ;

LAKNER, FJ ;

CAMPBELL, RA ;

HAGER, LP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (23) :6412-6413

[9] TRANSIENT HEME N-ALKYLATION OF CHLOROPEROXIDASE BY TERMINAL ALKENES AND ALKYNES [J].

DEXTER, AF ;

HAGER, LP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (02) :817-818

[10] THE SYNTHESIS OF AROMATIC DIVINYLOGS AND AROMATIC HALOGENATED VINYLOGS [J].

FRISCH, KC .

JOURNAL OF POLYMER SCIENCE, 1959, 41 (138) :359-367

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