Nonlinear optical properties of transition metal acetylides and their derivatives

被引：374

作者：

Powell, CE ^{[1
]}

Humphrey, MG ^{[1
]}

机构：

[1] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 7-8期

关键词：

acetylide complexes; alkynyl complexes; vinylidene complexes; nonlinear optics; hyperpolarizabilities; quadratic nonlinearities; cubic nonlinearities;

D O I：

10.1016/j.ccr.2004.03.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are summarized, and molecular structure-NLO property trends are developed. The origin of NLO effects in molecules is presented, and the advantages and shortcomings of experimental procedures that have been used to measure optical nonlinearities for these complexes are discussed. Attempts to "switch" optical nonlinearities of acetylide or vinylidene complexes are summarized. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：725 / 756

页数：32

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