Ru(CH3CN)3Cl3, preparation and use as a mediator for the electrooxidation of hydrocarbons

被引：14

作者：

Appelbaum, L

Heinrichs, C

Demtschuk, J

Michman, M ^{[1
]}

Oron, M

Schäfer, HJ

Schumann, H

机构：

[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel

[2] Univ Munster, Inst Organ Chem, D-48148 Munster, Germany

[3] Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 592卷 / 02期

关键词：

tris(acetonitrile)ruthenium trichloride; electrocatalysis; indirect electrooxidation; tetralin; tetralone;

D O I：

10.1016/S0022-328X(99)00532-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogenation of ruthenium chloride in acetonitrile yields complexes of the type Ru(CH3CN)(n)Cl6-n of which three are isolated (n = 2, 3, 4). Their formation is traced by voltammetry. Ru(CH3CN)(2)Cl-4 and Ru(CH3CN)(3)Cl-3 have been characterized by single-crystal X-ray diffraction. Voltammetry shows that Ru(CH3CN)(3)Cl-3 acts as a mediator for oxidation of cyclohexene, methylcyclohexene, 1-tetralol and tetralin. Its role in tetralin oxidation is illustrated by preparative scale electrolysis. The compounds Ru(CH3CN)(2)Cl-4 and Ru(CH3CN)(4)Cl-2 did not react with any of the mentioned hydrocarbons. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：240 / 250

页数：11

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