Fullerene tectonics .2. Synthesis and pyrolysis of halogenated benzo[c]phenanthrenes

被引：19

作者：

Plater, MJ

机构：

[1] Department of Chemistry, Aberdeen University, Aberdeen, AB24 3UE, Meston Walk

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 19期

关键词：

D O I：

10.1039/a701916e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Halogenated benzo[c]phenanthrenes with a halogen in the hindered fiord region are prepared by the photochemical cyclisation of appropriately substituted stilbenes. Pyrolysis gives the corresponding benzo[ghi]fluoranthrenes in moderate yields. At higher temperatures a competing rearrangement pathway to cyclopenta[cd]pyrene occurs.

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页码：2903 / 2909

页数：7

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