Aprotic diazotization in the presence of cuprous cyanide

被引：8

作者：

Giumanini, AG

Verardo, G

Geatti, P

Strazzolini, P

机构：

[1] Dept. of Chem. Sci. and Technologies, University of Udine

来源：

TETRAHEDRON | 1996年 / 52卷 / 20期

关键词：

D O I：

10.1016/0040-4020(96)00331-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In a procedure of extreme simplicity and rapidity a mixture of an aromatic primary amine, copper (I) cyanide and an alkyl nitrite in dimethyl sulphoxide yielded fair to moderate yields of the corresponding nitriles. Side processes observed were reduction (NH2 --> H), nitration (NH2 --> NO2) and hydroxylation (NH2 --> OH). In the case of polyhaloanilines halogen dance products could be detected. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7137 / 7148

页数：12

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