Kinetic modelling of the thermal degradation of polyamide-6 nanocomposite

被引:89
作者
Dabrowski, F [1 ]
Bourbigot, S [1 ]
Delobel, R [1 ]
Le Bras, M [1 ]
机构
[1] Univ Sci & Tech Lille Flandres Artois, ENSC Lille, Lab Genie Proc INteract Fluides Mat, F-59652 Villeneuve Dascq, France
关键词
D O I
10.1016/S0014-3057(99)00079-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, thermal behaviour of both polyamide-6 and polyamide-6 clay nanocomposite is studied. The Invariant Kinetic Parameters method enables modelling of the thermal degradation. The role played by oxygen during thermal degradation of polyamide-6 and polyamide-6 clay nanocomposite is investigated. The efficiency of the self-protective coatings which form during the pyrolysis and the thermo-oxidative degradation of polyamide-6 clay nanocomposite is discussed. The properties of these coatings are related to the previously observed improved fin properties of polyamide-6 clay nanocomposite as compared with polyamide-6. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:273 / 284
页数:12
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