Photoinduced morphological changes and optical writing in a liquid crystalline polymer on the micron and sub-micron scale

被引:9
作者
Camorani, P [1 ]
Cristofolini, L
Galli, G
Fontana, MP
机构
[1] Univ Parma, Ist Nazl Fis Mat, UdR Parma, Dipartimento Fis, I-43100 Parma, Italy
[2] Univ Pisa, Dipartimento Chim Gen & Inorgan Chim Analit Chim, Pisa, Italy
关键词
azobenzene; side chain polymeric liquid crystals; photoinduced surface relief;
D O I
10.1080/10587250210577
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper we describe our recent work on optical effects due to photoinduced molecular reorientation in a side chain liquid crystalline polymer, namely azo-polymethacrylate (PMA4). We have studied several kinds of optical effects on space scales ranging from the nanoscopic to macroscopic. In particular, we have built a computer controlled microscope-based apparatus to study photoinduced effects, down to the micron scale in thin and ultrathin (Langmuir Blodgett) films of our material. Furthermore we measured the morphology and the photoinduced surface deformation by Atomic Force Microscopy in the submicron scale.
引用
收藏
页码:175 / 184
页数:10
相关论文
共 12 条
[1]  
ALLEGRINI M, UNPUB
[2]   PHOTOCHROMIC LIQUID-CRYSTALLINE POLYMERS MAIN CHAIN AND SIDE-CHAIN POLYMERS CONTAINING AZOBENZENE MESOGENS [J].
ANGELONI, AS ;
CARETTI, D ;
CARLINI, C ;
CHIELLINI, E ;
GALLI, G ;
ALTOMARE, A ;
SOLARO, R ;
LAUS, M .
LIQUID CRYSTALS, 1989, 4 (05) :513-527
[3]  
ARISI S, 2001, IN PRESS MOL CRYST L
[4]   Molecular relaxation in a photosensitive liquid-crystalline polymeric glass former [J].
Cristofolini, L ;
Facci, P ;
Camorani, P ;
Fontana, MP .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (10A) :A355-A362
[5]   Glass transition and relaxation following photoperturbation in thin polymeric films [J].
Cristofolini, L ;
Arisi, S ;
Fontana, MP .
PHYSICAL REVIEW LETTERS, 2000, 85 (23) :4912-4915
[6]   Layering and relaxation in molecular films of a photosensitive polyacrylate from X-ray reflectivity and in elastic neutron scattering experiments [J].
Cristofolini, L ;
Fontana, MP ;
Konovalov, O .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 2002, 82 (05) :523-531
[7]  
Cristofolini L, 2001, PHYS REV E, V64, DOI 10.1103/PhysRevE.64.061803
[8]  
DEGENNES PG, 1974, PHYSICS LIQUID CRYST
[9]   An analysis of the anisotropic and topographic gratings in a side-chain liquid crystalline azobenzene polyester [J].
Holme, NCR ;
Nikolova, L ;
Ramanujam, PS ;
Hvilsted, S .
APPLIED PHYSICS LETTERS, 1997, 70 (12) :1518-1520
[10]   NOVEL SIDE-CHAIN LIQUID-CRYSTALLINE POLYESTER ARCHITECTURE FOR REVERSIBLE OPTICAL STORAGE [J].
HVILSTED, S ;
ANDRUZZI, F ;
KULINNA, C ;
SIESLER, HW ;
RAMANUJAM, PS .
MACROMOLECULES, 1995, 28 (07) :2172-2183