Ferrocene-substituted amidinate derivatives: Syntheses and crystal structures of lithium, iron(II), and cobalt(II) complexes

被引：64

作者：

Hagadorn, JR ^{[1
]}

Arnold, J ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 02期

关键词：

D O I：

10.1021/ic961058a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ferrocene-containing amidinate anion FcC(NCy)(2)](-) (Fc=ferrocenyl) is obtained by the reaction of N,N'-dicyclohexylcarbodiimide with FcLi in THF/hexanes. The lithium derivative reacts with 1/2 equiv of FeCl2 or CoBr2 to afford the trimetallic derivatives [FcC(NCy)(2)](2)M . nE(t)2O. X-ray crystal structures of the Li, Fe(II), and Co(II) derivatives are reported.

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页码：132 / &

页数：3

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