Layered rare-earth hydroxides:: A class of pillared crystalline compounds for intercalation chemistry

被引：220

作者：

Gandara, Felipe ^{[1
]}

Perles, Josefina ^{[1
]}

Snejko, Natalia ^{[1
]}

Iglesias, Marta ^{[1
]}

Gomez-Lor, Berta ^{[1
]}

Gutierrez-Puebla, Enrique ^{[1
]}

Monge, M. Angeles ^{[1
]}

机构：

[1] Inst Ciencia Mat Madrid, Madrid 20849, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 47期

关键词：

heterogeneous catalysis; hydrogen bonds; intercalations; layered compounds; rare earths;

D O I：

10.1002/anie.200602502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The combined advantages of layered double-hydroxide catalysts and rare-earth compounds are found in the layered rare-earth hydroxides [R4(OH)10(H2O)4] nAn (R = Y, Dy, Ho, Yb; A = organic anion). These crystalline materials (see structure) comprise rigid organic anions (balls and sticks) intercalated between inorganic layers (polyhedra). They are selective heterogeneous catalysts for hydrodesulfurization and sulfide oxidation. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：7998 / 8001

页数：4

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