The 5d4fn-1 → 4fn luminescence of trivalent rare earth ions in inorganic crystals

被引：6

作者：

Dorenbos, P ^{[1
]}

机构：

[1] Delft Univ Technol, Interfac Reactor Inst, NL-2629 JB Delft, Netherlands

来源：

RARE EARTHS '98 | 1999年 / 315-3卷

关键词：

5d4f(n-1) -> 4f(n) luminescence; fast scintillators; nephelauxetic effect;

D O I：

10.4028/www.scientific.net/MSF.315-317.222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Data on 5d4f (n-1) --> 4f (n) luminescence of the trivalent rare earth ions obtained from literature on luminescent phosphors, and from research on scintillation crystals has been gathered. More than 200 different inorganic compounds doped with Ce3+, Pr3+, or Nd3+ were found that show spin and dipole allowed 5d4f (n-1) --> 4f (n) transitions. Inspecting the wavelength of emission, clear patterns emerge that help in predicting the position of 5d4f (n-1) levels in yet non-investigated compounds.

引用

页码：222 / 227

页数：6

共 13 条

[1] ANTICFIDANCEV E, 1987, NEW J CHEM, V11, P467
[2] IMPACT OF ION-HOST INTERACTIONS ON THE 5D-TO-4F SPECTRA OF LANTHANIDE RARE-EARTH-METAL IONS .1. A PHENOMENOLOGICAL CRYSTAL-FIELD MODEL
AULL, BF
JENSSEN, HP
[J]. PHYSICAL REVIEW B, 1986, 34 (10): : 6640 - 6646
[3] BASIC AND APPLIED-RESEARCH ON PHOSPHORS BASED ON GADOLINIUM COMPOUNDS
BLASSE, G
[J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1992, 130 (02): : K85 - K89
[4] NEPHELAUXETIC EFFECT FOR 4FN CONFIGURATIONS IN SOLID-STATE
CARO, P
BEAURY, O
ANTIC, E
[J]. JOURNAL DE PHYSIQUE, 1976, 37 (06): : 671 - 676
[5] Scintillation properties of RbGd2Br7:Ce3+ crystals;: fast, efficient, and high density scintillators
Dorenbos, P
van't Spijker, JC
Frijns, OWV
van Eijk, CWE
Kramer, K
Gudel, HU
Ellens, A
[J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 132 (04) : 728 - 731
[6] Dubinskii M. A., 1985, Soviet Physics - Solid State, V27, P1315
[7] Piper W. W., 1974, Journal of Luminescence, V8, P344, DOI 10.1016/0022-2313(74)90007-6
[8] ENERGY-LOSS IN INORGANIC SCINTILLATORS
RODNYI, PA
DORENBOS, P
VANEIJK, CWE
[J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1995, 187 (01): : 15 - 29
[9] SCHARMER EG, 1982, THESIS U HAMBURG
[10] Luminescence of Pr3+ in SrAl12O19: Observation of two photon luminescence in oxide lattice
Srivastava, AM
Beers, WW
[J]. JOURNAL OF LUMINESCENCE, 1997, 71 (04) : 285 - 290

← 1 2 →