A pseudo-rotaxane based on an iridium(III)-copper(I) dyad

被引:13
作者
Baranoff, E
Griffiths, K
Collin, JP
Sauvage, JP
Ventura, B
Flamigni, L
机构
[1] Univ Strasbourg 1, Inst Le Bel, Lab Chim Organominerale, CNRS,UMR 7513, F-67070 Strasbourg, France
[2] CNR, Ist ISOF, I-40129 Bologna, Italy
关键词
D O I
10.1039/b407291j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a pseudo-rotaxane containing two metal centres has been achieved using the coordination of a ditopic organic ligand on an iridium(III) complex followed by the coordination of a copper(I) centre. Preliminary photophysical studies indicate that the excited state of the iridium is quenched by the copper unit.
引用
收藏
页码:1091 / 1095
页数:5
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