4-Triethylammoniomethyl-1,3-dioxolane-2-spiro-1′-2′,4′,6′-trinitrocyclohexadienide

被引:5
作者
Borbulevych, OY
Shishkin, OV
Knyazev, VN
机构
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia
[2] Natl Acad Sci Ukraine, STC Inst Single Crystals, Sci Res Dept Alkali Halide Crystals, UA-310001 Kharkov, Ukraine
[3] KA Timiryazev Agr Acad, Moscow 127550, Russia
关键词
D O I
10.1107/S0108270199009233
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In molecules of the title compound, C15H22N4O8, the geometry of the six-membered ring is typical for Meisenheimer complexes of 2,4,6-trinitrobenzene. However, the difference between the C-N bond lengths to the nitro groups in para and ortho positions with respect to the saturated C atom is less pronounced than in related compounds.
引用
收藏
页码:1918 / 1920
页数:3
相关论文
共 10 条
  • [1] Borbulevych OY, 1998, MONATSH CHEM, V129, P467
  • [2] FURMANOVA NG, 1980, ZH STRUKT KHIM, V21, P83
  • [3] Knyazev VN, 1996, ZH ORG KHIM+, V32, P1394
  • [4] KNYAZEV VN, 1995, ZH ORG KHIM+, V31, P3
  • [5] Dipolar spirocyclic sigma-complexes based on of 4,6-dinitrobenzofuroxan
    Kurbatov, SV
    Budarina, ZN
    Vaslyaeva, GS
    Borisenko, NI
    Knyazev, AP
    Minkin, VI
    Zhdanov, YA
    Olekhnovich, LP
    [J]. RUSSIAN CHEMICAL BULLETIN, 1997, 46 (08) : 1445 - 1448
  • [6] OLEKHNOVICH LP, 1982, ZH ORG KHIM+, V18, P465
  • [7] SHELDRICK GM, 1994, SHELXTL PLUS PC VERS
  • [8] *SIEM, 1989, P3 DIFFR CONTR PROGR
  • [9] *SIEM, 1991, XDISK DAT RED PROGR
  • [10] ZEFIROV YV, 1989, USP KHIM+, V58, P713