Thermal properties of poly(vinyl chloride)/montmorillonite nanocomposites

被引：175

作者：

Gong, FL ^{[1
]}

Feng, M ^{[1
]}

Zhao, CG ^{[1
]}

Zhang, SM ^{[1
]}

Yang, MS ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China

来源：

POLYMER DEGRADATION AND STABILITY | 2004年 / 84卷 / 02期

关键词：

poly(vinyl chloride); montmorillonite; nanocomposite; thermal properties;

D O I：

10.1016/j.polymdegradstab.2003.11.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(vinyl chloride)/montmorillonite (PVC/MMT) nanocomposites were synthesized via in situ intercalative polymerization and their thermal properties were examined by means of thermogravimetric analysis (TGA) and differential scanning calorimeter (DSC). The nanocomposites exhibited a little higher glass transition temperature in comparison with pure PVC. The presence of organophilic montmorillonite enhanced the rapidest decomposition temperature and reduced the maximum decomposition rate and the onset decomposition temperature. At high temperature, a compact char formed in the surface of the nanocomposites, obstructing the thermal degradation of the polymer matrix. The compact char surface was characterized by Fourier-transformed infrared spectrophotometer (FT-IR). (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：289 / 294

页数：6

共 26 条

[1] POLYMERIZATION OF ADSORBED MONOLAYERS .2. THERMAL DEGRADATION OF INSERTED POLYMER [J].