Synthesis of C60-diphenylaminofluorene dyad with large 2PA cross-sections and efficient intramolecular two-photon energy transfer

被引:51
作者
Chiang, LY [1 ]
Padmawar, PA
Canteenwala, T
Tan, LS
He, GS
Kannan, R
Vaia, R
Lin, TC
Zheng, QD
Prasad, PN
机构
[1] Univ Massachusetts, Dept Chem, Inst Nanosci & Engn, Lowell, MA 01854 USA
[2] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 10764, Taiwan
[3] AF Res Lab, MLBP, Polymer Branch, Wright Patterson AFB, OH 45433 USA
[4] SUNY Buffalo, Inst Lasers Photon & Biophoton, Buffalo, NY 14260 USA
关键词
D O I
10.1039/b202681c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first, highly two-photon active C-60 derivative comprised of a A-sp(3)-D conjugate structure was synthesized showing effective two-photon absorption cross-sections (sigma(2)' = 196 x 10(-48) cm(4) sec(-1) molecule(-1)) in the nanosecond regime among the best values for diphenylaminofluorene-based AFX chromophores.
引用
收藏
页码:1854 / 1855
页数:2
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