Adsorption of water on the NaCl(001) surface. II. An infrared study at ambient temperatures

被引：125

作者：

Foster, MC ^{[1
]}

Ewing, GE ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 15期

关键词：

D O I：

10.1063/1.481256

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water adsorbed on the (001) face of NaCl under ambient conditions has been studied by infrared spectroscopy. From these measurements, combined with recent Monte Carlo calculations, we find evidence of two structures for the adsorbed water. At low coverages, the water molecules aggregate into islands on the surface. When a critical concentration is reached, multilayer growth becomes favorable, creating a thin film on the surface with properties similar to liquid water. (C) 2000 American Institute of Physics. [S0021-9606(00)70315-1].

引用

页码：6817 / 6826

页数：10

共 64 条

[1]

ADAMSON AW, 1982, PHYSICAL CHEM SURFAC

[2] MECHANISM OF CHARGE-TRANSFER BETWEEN COLLIDING ICE PARTICLES IN THUNDERSTORMS [J].